Document Type : Original Research Article


1 MSc. Chemical Engineering Department, Abadan Petrochemical Company, Abadan, Iran

2 PHd. Chemical Engineering Department, Persian Gulf Fajr Energy Co., Iran


In this study, the effect of nanoparticle of graphene oxide and surfactant sodium dodecyl sulfate (sds) 400 ppm on the storage capacity of co2 in hydrate was investigated. A laboratory system was developed for hydrate formation experiments. The experiments were carried out in the range of pressure 36-40 bar, temperature range from 273.35 k to 278.65 k, in the presence of graphene oxide and sodium dodecyl sulfate. Experimental results showed that by increasing the pressure at constant temperature for net water, storage capacity increased by 11%, and the storage capacity increased by 14% by decreasing the temperature at the constant pressure (36 bar). Adding sds increased storage capacity by 26%, while adding graphene oxide increased 4.2% of storage capacity. For this purpose, design expert software and response surface test method and historical method were used. Also, a mathematical equation was proposed to estimate the co2 storage capacity in hydrate.

Graphical Abstract

Effects of graphene oxide (GO) nanoparticle and SDS on storage capacity of CO2 in hydrate


Main Subjects

[1] A.A. Khokar, J.S. Gudmundssom, E.D. Sloan, Fluid Ph. Equilibria, 1998, 150-151, 383-392. [crossref], [Google Scholar], [Publisher]
[2] F. Zare Kazemabadi, A. Heydarinasab, A. Akbarzadeh, M. Ardjmand, ARTIF CELL NANOMED B., 2019, 47, 3222-3230. [crossref], [Google Scholar], [Publisher]
[3] F. Wang, S. Fu, G. Guo, Z.Z. Jia, R.B. Guo, Energy, 2016, 104, 76-84. [crossref], [Google Scholar], [Publisher]
[4] A. Bozorgian, A. Samimi, Int. J. New Chem., 2021, 8, 41-58. [crossref], [Google Scholar], [Publisher]
[5] A. Samimi, M. Samimi, J. Eng. Indu. Res., 2021, 2, 1-6. [crossref], [Google Scholar], [Publisher]
[6] Z. Ma, P. Zhang, H. Bao, S. Deng, Renew Sustain Energy Rev., 2016, 53, 1273-1302. [crossref], [Google Scholar], [Publisher]
[7] S. Muromachiu, A. Shijima, H. Miyamoto, R. Ohmura, J. Chem. Thermodynamics, 2015, 85, 94–100. [crossref], [Google Scholar], [Publisher]
[8] M. Yang, Y. Song, L. Jiang, Y. Zhao, X. Ruan, Y. Zhang, Sh. Wang, Appl. Energy, 2014, 116, 26–40. [crossref], [Google Scholar], [Publisher]
[9] W. Lee, Y.S. Kim, S.P. Kang, Chem. Eng. J., 2018, 331, 1-7. [crossref], [Google Scholar], [Publisher]
[10] Y.S. Yu, S.D. Zhou, X.S. Li, S.l. Wang, Fluid Ph. Equilibria, 2016, 414, 23-28. [crossref], [Google Scholar], [Publisher]
[11] M. Yang, W. Jing, P. Wang, L. Jiang, Y. Song, Fluid Ph. Equilibria, 2015, 401, 27-33. [crossref], [Google Scholar], [Publisher]
[12] M. Zbuzant, J. Eng. Indu. Res. 2020, 1, 75-81. [crossref], [Google Scholar], [Publisher]
[13] A. Mohammadi, M. Manteghian, A. Haghtalab, A.H. Mohammadi, M. Rahmati-Abkenar, Chem. Eng. J., 2014, 237, 387–395. [crossref], [Google Scholar], [Publisher]
[14] F. Zare Kazemabadi, A. Heydarinasab, A. Akbarzadehkhiyavi, M. Ardjmand, Chem. Methodol., 2021, 5, 135-152. [crossref], [Google Scholar], [Publisher]
[15] Y. Raziani, S. Raziani, J. Chem. Rev., 2021, 3, 83-96. [crossref], [Google Scholar], [Publisher]
[16] A. Ahmad, A. Sadrodin Reyazi, J. Eng. Indu. Res., 2021, 2, 134-160. [crossref], [Google Scholar], [Publisher]
[17] Y. Raziani, S. Raziani, Int. J. Adv. Stu. Hum. Soc. Sci., 2020, 9, 262-280. [crossref], [Google Scholar], [Publisher]
[18]  N. Kayedi, A. Samimi, M. Asgari Bajgirani, A. Bozorgian, S. Afr. J. Chem. Eng., 2021, 35, 153-158. [crossref], [Google Scholar], [Publisher]
[19]  E. Amouzad Mahdiraji; M. Sedghi Amiri, J. Eng. Indu. Res. 2020,2, 111-122. [crossref], [Google Scholar], [Publisher]  
[20]  S. Delavari, H. Mohammadi Nik, N. Mohammadi, A. Samimi, S.Y. Zolfegharifar, F Antalovits, L. Niedzwiecki, R. Mesbah, Chem. Methodol., 2021, 5, 178-189. [crossref], [Google Scholar], [Publisher]
[21] F. Rebout, Journal of Engineering in Industrial Research, 2020, 1, 19-37. [crossref], [Google Scholar], [Publisher]    
[22] K.L. Han, J. Eng. Indu. Res., 2020, 1, 38-50. [crossref], [Google Scholar], [Publisher]    
[23] F. Gharekhani Kasa, J. Eng. Indu. Res., 2020, 1, 51-74. [crossref], [Google Scholar], [Publisher]